<ul> or <ol>

<ul class="nav">
  <li class="nav-item">
    <a class="nav-link active" aria-current="page" href="#">Active</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link disabled">Disabled</a>
  </li>
</ul>

Without <ul> or <ol>

<nav class="nav">
  <a class="nav-link active" aria-current="page" href="#">Active</a>
  <a class="nav-link" href="#">Link</a>
  <a class="nav-link" href="#">Link</a>
  <a class="nav-link disabled">Disabled</a>
</nav>

Horizontal

<ul class="nav justify-content-center">
  <li class="nav-item">
    <a class="nav-link active" aria-current="page" href="#">Active</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link disabled">Disabled</a>
  </li>
</ul>

End

<ul class="nav justify-content-end">
  <li class="nav-item">
    <a class="nav-link active" aria-current="page" href="#">Active</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link disabled">Disabled</a>
  </li>
</ul>

<ul> and <li>

<ul class="nav flex-column">
  <li class="nav-item">
    <a class="nav-link active" aria-current="page" href="#">Active</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link disabled">Disabled</a>
  </li>
</ul>

Without <ul> or <ol>

<nav class="nav flex-column">
  <a class="nav-link active" aria-current="page" href="#">Active</a>
  <a class="nav-link" href="#">Link</a>
  <a class="nav-link" href="#">Link</a>
  <a class="nav-link disabled">Disabled</a>
</nav>

<ul class="nav nav-tabs">
  <li class="nav-item">
    <a class="nav-link active" aria-current="page" href="#">Active</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link disabled">Disabled</a>
  </li>
</ul>

With Dropdowns

<ul class="nav nav-tabs">
  <li class="nav-item">
    <a class="nav-link active" aria-current="page" href="#">Active</a>
  </li>
  <li class="nav-item dropdown">
    <a class="nav-link dropdown-toggle" data-bs-toggle="dropdown" href="#" role="button" aria-expanded="false">Dropdown</a>
    <ul class="dropdown-menu">
      <li><a class="dropdown-item" href="#">Action</a></li>
      <li><a class="dropdown-item" href="#">Another action</a></li>
      <li><a class="dropdown-item" href="#">Something else here</a></li>
      <li><hr class="dropdown-divider"></li>
      <li><a class="dropdown-item" href="#">Separated link</a></li>
    </ul>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link disabled">Disabled</a>
  </li>
</ul>

<ul class="nav nav-pills">
  <li class="nav-item">
    <a class="nav-link active" aria-current="page" href="#">Active</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link disabled">Disabled</a>
  </li>
</ul>

With Dropdowns

<ul class="nav nav-pills">
  <li class="nav-item">
    <a class="nav-link active" aria-current="page" href="#">Active</a>
  </li>
  <li class="nav-item dropdown">
    <a class="nav-link dropdown-toggle" data-bs-toggle="dropdown" href="#" role="button" aria-expanded="false">Dropdown</a>
    <ul class="dropdown-menu">
      <li><a class="dropdown-item" href="#">Action</a></li>
      <li><a class="dropdown-item" href="#">Another action</a></li>
      <li><a class="dropdown-item" href="#">Something else here</a></li>
      <li><hr class="dropdown-divider"></li>
      <li><a class="dropdown-item" href="#">Separated link</a></li>
    </ul>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link disabled">Disabled</a>
  </li>
</ul>

Fill

<ul class="nav nav-pills nav-fill">
  <li class="nav-item">
    <a class="nav-link active" aria-current="page" href="#">Active</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Much longer nav link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link disabled">Disabled</a>
  </li>
</ul>

Justified

<ul class="nav nav-pills nav-justified">
  <li class="nav-item">
    <a class="nav-link active" aria-current="page" href="#">Active</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Much longer nav link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link" href="#">Link</a>
  </li>
  <li class="nav-item">
    <a class="nav-link disabled">Disabled</a>
  </li>
</ul>